← Back
2013 National Semi Final chemistry Topic 13 Free

Water hardness and softening

Cations responsible for permanent water hardness · Sub-topic 1

SEMI FINAL STAGE 2013

MfantsiMan Girls

Adisadel College

St Peter's SHS


QUESTION

Name any three cations whose presence in water may cause permanent hardness.

ANSWER: Calcium²⁺, Magnesium²⁺, and Iron²⁺

SOLUTION:

These form insoluble salts with soap and are not removed by boiling (unlike temporary hardness).


---


PRACTICE QUESTIONS

1. QUESTION: Name two anions associated with permanent hardness of water.

ANSWER: Sulfate ($SO_4^{2-}$) and chloride ($Cl^-$)

SOLUTION:

Calcium and magnesium sulfates and chlorides are not removed by boiling.


2. QUESTION: Name the anion responsible for temporary hardness of water.

ANSWER: Hydrogencarbonate ($HCO_3^-$)

SOLUTION:

Calcium and magnesium hydrogencarbonates decompose on boiling.


3. QUESTION: Name one method of removing permanent hardness.

ANSWER: Any one of: adding washing soda, ion exchange, or distillation

SOLUTION:

These remove the $Ca^{2+}$ and $Mg^{2+}$ ions, which boiling cannot.


4. QUESTION: Name the cation, other than $Ca^{2+}$, mainly responsible for the hardness of water.

ANSWER: Magnesium ion ($Mg^{2+}$)

SOLUTION:

Calcium and magnesium ions both form scum with soap.


5. QUESTION: Name one method of removing temporary hardness.

ANSWER: Boiling (or adding slaked lime)

SOLUTION:

Both convert the hydrogencarbonates into insoluble carbonates.


6. QUESTION: Name the insoluble substance deposited when temporarily hard water is boiled.

ANSWER: Calcium carbonate (scale)

SOLUTION:

$Ca(HCO_3)_2\rightarrow CaCO_3+CO_2+H_2O$.