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2018 National One Eighth chemistry Topic 36 Free

Industrial and building-materials chemistry

Cement chemistry: source of calcium in clinker · Sub-topic 1

ONE-EIGHTH STAGE 2018

Prempeh College: 62 points

St. Francis Xavier: 29 points

Saviour SHS: 18 points


ROUND 1

QUESTION

Name the main source of the calcium in clinker, and describe the process(es) that raw material goes through during the formation of clinker.

ANSWER: Limestone (calcium carbonate, CaCO$_3$)

NOTE: The process part of the question: limestone is crushed, mixed with clay and heated in a rotary kiln; it decomposes to calcium oxide and carbon dioxide, and the calcium oxide combines with the silica and alumina of the clay to form calcium silicates and aluminates, which fuse into clinker.


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PRACTICE QUESTIONS

1. QUESTION: Name the main raw material that supplies the silica and alumina in cement clinker.

ANSWER: Clay (or shale)

SOLUTION:

Clay is an aluminosilicate; in the kiln it combines with calcium oxide to form calcium silicates and aluminates.


2. QUESTION: Name the gas released when limestone decomposes in a cement kiln.

ANSWER: Carbon dioxide

SOLUTION:

$CaCO_3\rightarrow CaO+CO_2$


3. QUESTION: Name the substance added to clinker when it is ground to make cement, and state its purpose.

ANSWER: Gypsum (calcium sulfate); it slows down the setting of the cement.

SOLUTION:

Without gypsum, the cement would set too quickly to be worked.


4. QUESTION: Name the type of kiln in which cement clinker is made.

ANSWER: A rotary kiln

SOLUTION:

The slowly turning, sloping kiln moves the raw mix towards the hottest zone.


5. QUESTION: What happens when cement is mixed with water and left to stand?

ANSWER: It reacts with the water (hydrates) and sets into a hard mass.

SOLUTION:

The calcium silicates form hydrated crystals that bind together.


6. QUESTION: What name is given to a mixture of cement, sand, stones and water that sets hard?

ANSWER: Concrete

SOLUTION:

Steel rods set inside it give reinforced concrete.