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2018 National Preliminary chemistry Topic 27 Free

Isotopes and mass spectrometry

Riddle: the mass spectrometer · Sub-topic 1

PRELIMINARY STAGE 2018


ROUND 2 - SPEED RACE

SPEED RACE (RIDDLES)

Sonrise SHS: 49 points

Opoku Ware School (OWASS): 46 points

Berekum SHS: 15 points

RIDDLE

I am an emitter of some sort.

I do not need electromagnetic radiation to function.

I work best with gases, but never mind — I have a chamber for vaporising solids and liquids too.

Who am I?

ANSWER: Mass spectrometer

EXPLANATION:

A mass spectrometer ionises a sample (an "emitter" of ions, via electron bombardment rather than electromagnetic radiation), then accelerates and deflects the ions through a magnetic field to separate them by mass-to-charge ratio; while it operates most simply with gaseous samples, an inlet/vaporisation chamber allows solid and liquid samples to be vaporised first.


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PRACTICE QUESTIONS

1. RIDDLE:

I am an analytical instrument.

I pass heat-carrying radiation through a sample.

Bonds in the sample absorb my radiation and vibrate.

I detect functional groups such as C=O and O–H.

My readout is plotted against wavenumber.

Breathalysers use my principle to detect ethanol.

Who am I?

ANSWER: INFRARED SPECTROMETER

EXPLANATION:

Infrared spectroscopy identifies bonds from the frequencies they absorb.


2. RIDDLE:

I am an instrument with a glass electrode.

I measure the hydrogen ion concentration of solutions.

My readings usually run from 0 to 14.

I must be calibrated with buffer solutions.

I am more precise than universal indicator.

My reading tells how acidic or alkaline a solution is.

Who am I?

ANSWER: PH METER

EXPLANATION:

A pH meter measures the potential of a glass electrode.


3. RIDDLE:

I am an evacuated glass vessel.

J.J. Thomson used me to discover the electron.

A high voltage drives a beam from my negative electrode.

Magnetic and electric fields bend my beam.

My beam makes a fluorescent screen glow.

Old television sets were built around me.

Who am I?

ANSWER: CATHODE RAY TUBE

EXPLANATION:

Cathode rays are streams of electrons.


4. RIDDLE:

I am an analytical instrument.

I turn samples into positive ions.

A magnetic field bends my ions by different amounts.

I sort ions by the ratio of their weight to their charge.

I find the relative abundances of isotopes.

Aston built an early version of me.

Who am I?

ANSWER: MASS SPECTROMETER

EXPLANATION:

A mass spectrometer separates ions by their mass-to-charge ratio.


5. RIDDLE:

I am a long glass tube with a tap.

My scale is marked in cubic centimetres.

I deliver accurately measured volumes of liquid.

I am used in titrations.

I am read at the bottom of the meniscus.

I am clamped vertically above a conical flask.

Who am I?

ANSWER: BURETTE

EXPLANATION:

A burette measures the volume of titrant added.


6. RIDDLE:

I split light into its colours.

I use a prism or a diffraction grating.

I show the line spectra of elements.

Helium was first found on the Sun with me.

Bunsen and Kirchhoff discovered caesium with me.

I identify metals in flame tests precisely.

Who am I?

ANSWER: SPECTROSCOPE

EXPLANATION:

Each element has its own pattern of spectral lines.