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2026 National Preliminary chemistry Topic 19 Free

Empirical and molecular formula determination

Empirical formula of an oxide from percent composition and atomic mass · Sub-topic 1

PRELIMINARY STAGE 2026

Contest 10

Tema Secondary School: 42 points

St. Paul's SHS, Denu: 31 points

Tarkwa SHS: 29 points

Contest 11

Ghanata SHS: 51 points

O’Reilly SHS: 43 points

Yendi SHS: 22 points

Contest 12

St. Joseph Seminary SHS: 52 points

KNUST SHS: 39 points

SDA SHS, Agona: 28 points


ROUND 2 - SPEED RACE

QUESTION

Determine the empirical formula of an oxide of an element X that contains 30.4% by mass of X, given that the atomic mass of X is 14 g/mol.

NOTE: An atomic mass of 14 identifies X as nitrogen, so the oxide is NO$_2$, not SO$_2$.

The calculation gives NO$_2$, corrected here (likely a mishearing of "N-O-2" as "S-O-2").

ANSWER: NO$_2$

SOLUTION:

$\text{O} = 100-30.4$

$\text{O} = 69.6\%$

$\text{Moles X} = \dfrac{30.4}{14}$

$\text{Moles X} = 2.17$

$\text{moles O} = \dfrac{69.6}{16}$

$\text{moles O} = \dfrac{696\times10^{-1}}{16}$

$\text{moles O} = \dfrac{87}{2} \times10^{-1}$

$\text{moles O} = 4.35$

Ratio O:

$\text{X} = \dfrac{4.35}{2.17}$

$\text{X} \approx 2$

Empirical formula $=$ XO$_2$ $=$ NO$_2$ (since X, atomic mass 14, is nitrogen).


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PRACTICE QUESTIONS

1. QUESTION: Determine the empirical formula of an oxide of an element X that contains 40.0% by mass of X, given that the atomic mass of X is 32 g/mol. (O = 16)

ANSWER: $XO_3$

SOLUTION:

$\%O = 100 - 40.0$

$\%O = 60.0\%$

$\text{moles X} = \dfrac{40.0}{32}$

$\text{moles X} = \dfrac{5}{4}$

$\text{moles X} = 1.25$

$\text{moles O} = \dfrac{60.0}{16}$

$\text{moles O} = \dfrac{15}{4}$

$\text{moles O} = 3.75$

$X : O = 1 : 3$

Empirical formula: $XO_3$


2. QUESTION: Determine the empirical formula of an oxide of an element X that contains 60.0% by mass of X, given that the atomic mass of X is 24 g/mol. (O = 16)

ANSWER: $XO$

SOLUTION:

$\%O = 100 - 60.0$

$\%O = 40.0\%$

$\text{moles X} = \dfrac{60.0}{24}$

$\text{moles X} = \dfrac{5}{2}$

$\text{moles X} = 2.50$

$\text{moles O} = \dfrac{40.0}{16}$

$\text{moles O} = \dfrac{5}{2}$

$\text{moles O} = 2.50$

$X : O = 1 : 1$

Empirical formula: $XO$


3. QUESTION: Determine the empirical formula of an oxide of an element X that contains 60.0% by mass of X, given that the atomic mass of X is 48 g/mol. (O = 16)

ANSWER: $XO_2$

SOLUTION:

$\%O = 100 - 60.0$

$\%O = 40.0\%$

$\text{moles X} = \dfrac{60.0}{48}$

$\text{moles X} = \dfrac{5}{4}$

$\text{moles X} = 1.25$

$\text{moles O} = \dfrac{40.0}{16}$

$\text{moles O} = \dfrac{5}{2}$

$\text{moles O} = 2.50$

$X : O = 1 : 2$

Empirical formula: $XO_2$


4. QUESTION: Determine the empirical formula of an oxide of an element X that contains 40.0% by mass of X, given that the atomic mass of X is 16 g/mol. (O = 16)

ANSWER: $X_2O_3$

SOLUTION:

$\%O = 100 - 40.0$

$\%O = 60.0\%$

$\text{moles X} = \dfrac{40.0}{16}$

$\text{moles X} = \dfrac{5}{2}$

$\text{moles X} = 2.50$

$\text{moles O} = \dfrac{60.0}{16}$

$\text{moles O} = \dfrac{15}{4}$

$\text{moles O} = 3.75$

$X : O = 2 : 3$

Empirical formula: $X_2O_3$


5. QUESTION: Determine the empirical formula of an oxide of an element X that contains 80.0% by mass of X, given that the atomic mass of X is 64 g/mol. (O = 16)

ANSWER: $XO$

SOLUTION:

$\%O = 100 - 80.0$

$\%O = 20.0\%$

$\text{moles X} = \dfrac{80.0}{64}$

$\text{moles X} = \dfrac{5}{4}$

$\text{moles X} = 1.25$

$\text{moles O} = \dfrac{20.0}{16}$

$\text{moles O} = \dfrac{5}{4}$

$\text{moles O} = 1.25$

$X : O = 1 : 1$

Empirical formula: $XO$


6. QUESTION: Determine the empirical formula of an oxide of an element X that contains 60.0% by mass of X, given that the atomic mass of X is 12 g/mol. (O = 16)

ANSWER: $X_2O$

SOLUTION:

$\%O = 100 - 60.0$

$\%O = 40.0\%$

$\text{moles X} = \dfrac{60.0}{12}$

$\text{moles X} = 5.00$

$\text{moles O} = \dfrac{40.0}{16}$

$\text{moles O} = \dfrac{5}{2}$

$\text{moles O} = 2.50$

$X : O = 2 : 1$

Empirical formula: $X_2O$